How do I safely eject the roll cassette?

Press and hold the cassette button for 2 seconds, and when the cassette button's LED is off, you can safely remove the roll cassette. To remove it, lift it up slightly and away from your printer. Do not try to remove a roll cassette when the LED is blinking or remains lit. (Page 12)

From the official Brother VC-500W Color Label Printer manual, page 12

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