How do I pair the thermostat with the receiver?

Access parameter P05 in the thermostat's parameter menu, then press and hold the button on the receiver for 3 seconds. The green LED will flash to indicate it is ready to pair, and the receiver will stop flashing once pairing is complete. Note that pairing is a factory default setting and should already be configured out of the box. (Page 26)

From the official Bosch RT20 Rf Room Thermostat manual, page 26

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