Why is my air conditioner not cooling the room effectively?
Several issues can reduce cooling performance, including restricted airflow from curtains or furniture blocking the unit, a dirty air filter, or the thermostat not being set cool enough. You should also close the vent for maximum cooling efficiency, as opening it allows internal air to escape. If the unit was just turned on, allow some time for the room temperature to adjust. (Page 19)
From the official LG LWG07-Series Window Air Conditioner manual, page 19
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